Acetylene Chemistry: “acetylenic Tree” in Organic Synthesis on the Eve of Xxi Century
نویسنده
چکیده
В первой статье, посвященной химии ацетилена [1], были рассмотрены строение и реакционная способность алкинов, включая строение и реакции π -комплексов алкинов с переходными металлами. Высокая реакционная способность С ≡ Си ≡ С–Н-связей в алкинах делает их участниками разнообразнейших реакций, составляющих основу раздела органической синтетической и промышленной химии, который называется “химия ацетилена” [2]. В этой статье будут рассмотрены реакции, сыгравшие важную роль в промышленном органическом синтезе, но переставшие быть экономически эффективными или экологически приемлемыми, и процессы, по-прежнему занимающие важное место в химической практике. Будет рассказано также о реакциях, которые, несомненно, найдут применение в промышленной химии XXI века.
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